Chemistry – Aditanar College of Arts and Science

CHEMISTRY RESEARCH CENTRE

The Department of Chemistry was recognized as a Research Centre by Manonmaniam Sundaranar University, Tirunelveli for pursuing research in Chemistry on April 2007. Dr. C. Kavitha, Associate Professor of Chemistry is serving as the Head for the research centre. At present, five faculty members are approved as Ph.D. guides by Manonmaniam Sundaranar University, Tirunelveli and four scholars are pursuing their Ph.D. degree in various fields of chemistry under their guidance in our Research Centre.

Objectives of the Research Centre

To stimulate academic environment for promotion of quality research.
To establish synergistic collaboration with national and international organizations.
To compete with the scholars of the national and international community.
To create awareness of the latest developments in the field of chemistry.

Features of the Research Centre

The research centre is networked with broad-band internet round the clock and INFLIBNET network of UGC can be accessed
There is an air-conditioned instrumentation room equipped with sophisticated UV-Visible spectrophotometer for analytical purpose.
One major research project funded by UGC and three minor research projects funded by different agencies have been completed.
So far more than 140 research papers have been published in reputed national and international journals.
We have organized two international seminars and published proceedings with the ISBN number.

Details about the Research Projects

The research activities of the centre are assisted by various agencies like UGC, Madurai Kamaraj University and the Management of Aditanar College. The funded projects of Dr. P. Subramaniam are:

S.No	Title of the Project	Nature of the Project	Funding Agency	Period	Status
1	Micellar Effect on the Fe(III) and Cr(III)-Salen Catalysed Redox Reactions of Methionines and Thioether containing Organic Compounds	Major	UGC	2011-2014	Completed
2	Electron Transfer Reactions of Polypyridine-Metal Complexes with Aromatic Sulphur Compounds	Minor	UGC	2007-2009	Completed
3	Mechanistic and structural studies on disulphides	Minor	UGC	1988- 1990	Completed
4	¹³C NMR spectral study of ortho-effect in phenyl-mercaptoacetic acids and phenylsulphonylacetic acids	Minor	Madurai Kamaraj University	1987-1989	Completed

Details about the Scholars

Twenty three scholars have successfully completed their Ph.D. degree and four scholars have submitted their thesis. More than 40 students have under taken their M.Phil. degree from our research centre.

S.No	Name of the Scholar	Title of the thesis	Status
1	Mr. K. Sathiyaseelan	Developments, Synthesis, Characterization and Host-guest Complexation studies of Supramolecular Host Molecules with Some Selected Guest Molecules	Submitted in Mar 2024
2	Ms. T. Kodispathi	Development of conducting polymer based composites for environmental applications	Submitted in Jan 2024
3	Mrs. R. Umadevi	Fabrication and Characterization of electrically conductive composites for novel applications	Submitted in Dec 2023
4	Mr. M. Madhusudhan	Dissolution behaviour of carbon steel in acid Containing inhibitor	Submitted in July 2023
5	Mr. M. Bala	Inhibition Efficiency of Inhibitor on Metals	Awarded in May 2024
6	Mrs. T. Amutha	Investigations on conducting polymeric composite materials for analytical applications	Awarded in Dec 2023
7	Mrs. C. Sangeetha	Corrosion inhibition and absorption properties of Green plant extract on metals in acid nvironment	Awarded in July 2023
8	Mrs. P. Muhambihai	Synthesis, Characterization and Applications of Nanomaterials – Nanoparticles and Nanocomposites	Awarded in Feb 2023
9	Mrs. Michlin Ruphina Maragadham	Corrosion behaviour of mild steel using green plant extract in acid media	Awarded in Aug 2021
10	Mrs. C. Kavitha	Salen Mediated Reactions and Linear Free Energy Relationships	Awarded in Mar 2021
11	Mrs. N. Kohila	Synthesis, ion-Exchange Behavior and Environmental Applications of Organic-Inorganic Hybrid Materials	Awarded in Mar 2021
12	Mr. M. Maria Albert Denison	Synthesis and Spectral investigation of some transition metal complexes with carboxyamides	Awarded in Dec 2018
13	Mrs. S. Selvakumari	Studies on the effect of additives on zinc-cobalt alloy electrodeposition and their characterization	Awarded in Dec 2018
14	Mrs. C. Shanmuga Sundari	Oxygenation Reactions of Organic Sulfur Compounds with Metal Complexes–Kinetic and Mechanistic Approach	Awarded in Mar 2018
15	Mrs. R. Jeevi Esther Rathnakumari	A Mechanistic Study of Redox Reactions	Awarded in Sep 2017
16	Mr. S. Anbarasan	Generation Generation of Oxometal Ion and its Reactivity with Biologically Important Organic Sulphur Compounds of Oxometal Ion and its Reactivity with Biologically Important Organic Sulphur Compounds	Awarded in Sep 2017
17	Mrs. S. Shobana	Synthesis, Structural and Stability studies of some transition metal complexes	Awarded in Aug 2017
18	Mrs. J. Janet Sylvia Jaba Rose	Mechanism of Electron Transfer Reactions in Organic Sulphur Compounds	Awarded in July 2017
19	Mrs. S. Sugirtha Devi	Electron Transfer Reactions of Metal Complexes with Organic Compounds	Awarded in Aug 2015
20	Mrs. A.G. Annaselvi	Utility of Cyclodextrins In Agriculture: Synthesis and Characterization of Inclusion Complexes Between Cyclodextrins and Some Herbicides	Awarded in June 2015
21	Mrs. M. Jansi Rani	Application of Low Cost Carbon And Biomaterials for Toxic Pollutants Removal From Aqueous Systems	Awarded in June 2015
22	Mrs. N. Thamil Selvi	Dynamics and Mechanism of Some Electron Transfer Reactions	Awarded in Jan 2015
23	Mrs. K. Jacinth Mispa	Studies on Conducting Polymeric Composite Materials	Awarded in Mar 2014
24	Mrs. G. Revathi	Adsorption Kinetics involving Low cost Carbon	Awarded in Feb 2013
25	Mr. A. Vijaya Kumar	Kinetics and Equilibrium Studies on the Removal of Dyes by Adsorption onto Activated Carbons Prepared from Tree Leaves	Awarded in Feb 2012
26	Mr. P. Balakumar	Studies in Electron Transfer Reactions	Awarded in Dec. 2010
27	Ms. D. Sweetlin Rajula Rubavathi	Electron Transfer Reactions of Iron(III) and Cobalt(III) Complexes in Reverse Micelles	Awarded in July 2010

The following scholars are pursuing doctoral studies in the research centre

S.No	Name	Area of Research	Category
Guide Name: Dr. P. Deepa Rani
1	Mrs. Myhthili Prasanna	Nano structured metal oxide and its polymer composites –Development and its catalysis	Part-time
2	Mrs. Chandra	Removal of toxic pollutants using polyaniline and chitosan composites	Part-time
Guide Name: Dr. I. Abulkalam Azath (Co-guide)
3	Mrs. V. Suganya	Removal of pollutants using polyaniline based composites	Full-time
Guide Name: Dr. A. Antony Muthu Prabhu
4	Mrs. K. Sivasaranya	Synthesis, characterization and Biological Activity of Coumarin Derivatives	Part-time

Details about the research papers published by Dr. C. Kavitha

Alteration of electronic effect causes change in mechanism: vanadium salen catalysed sulfoxidation of phenylmercapto acetic acids, C. Kavitha and P. Subramaniam, Polyhedron, 175, 114172-114183 (2020)

Competitive behavior of nitrogen based axial ligands in the oxovanadium(IV)-salen catalyzed sulfoxidation of phenylmercaptoacetic acid, C. Kavitha and P. Subramaniam, Polyhedron, 189, 114712-114724 (2020).

Role of trichloroacetic acid in the catalytic activity of oxovanadium(IV)-salen in the sulfoxidation of phenylmercaptoacetic acids, C. Kavitha and P. Subramaniam, Polyhedron, 218, 115779, (2022).

Impact of added ligand oxides in the sulfoxidation of phenylmercaptoacetic acids with oxovanadium (IV)-salen complexes, C. Kavitha and P. Subramaniam, J. Phy. Org. Chem., 36, e4483 , (2022).

Adsorption and electrochemical studies of thio acetamide inhibitor on gas pipeline metal in natural sea water environment, Mathusuthan, P. Deepa Rani, C. Kavitha, Eur. Chem. Bull., 12 (2023).

Dual role of water in the oxygenation of phenylmercaptoacetic acids catalyzed by [oxo(salen)chromium(V)]⁺ PF₆^–, C. Kavitha, S. Anbarasan and P. Subramaniam, Polyhedron, 247, 116712, (2024).

Relative reactivity of Oxovanadium(IV)-Salophen complexes and impeding effect of nitrogen bases in the oxidation of phenylsulfinylacetic acid by hydrogen peroxide, R. Jeevi Esther Rathnakumari, C. Kavitha, J. Janet Silvia Jebarose, P. Subramaniam, C. Vetriselvi, J. Creat. Res. Thoughts., 12(4), i434-i446 (2024).

A mechanistic study of the oxidative decarboxylation of phenylsulfinylacetic acids by hydrogen peroxide catalyzed by Oxovanadium(IV)-Salophen complexes in the presence of bases-a non linear hammett and linear Yukawa Tsuno correlation, R. Jeevi Esther Rathnakumari, C. Kavitha, J. Janet Silvia Jebarose, P. Subramaniam, C. Vetriselvi, J. Emerg. Technol. Innov. Res., 11(4) j91-j102 (2024).

A mechanistic study of the Oxovanadium(IV)-Salophen catalyzed oxidative decarboxylation of phenylsulfinylacetic acids by hydrogen peroxide in the presence of ligand oxides -a non linear Hammett correlation, R. Jeevi Esther Rathnakumari, C. Kavitha, J. Janet Silvia Jebarose, P. Subramaniam, C. Vetriselvi, J. Creat. Res. Thoughts., 12(4), k689-k699, (2024).

Restraining role of ligand oxides and relative reactivity of Oxovanadium(IV)-Salophen complexes in the catalytic oxidation of phenylsulfinylacetic acids by hydrogen peroxide, R. Jeevi Esther Rathnakumari, C. Kavitha, J. Janet Silvia Jebarose, P. Subramaniam, C. Vetriselvi, J. Emerg. Technol. Innov. Res., 11(4), k508-k520, (2024).

A mechanistic study of the electron transfer reactions in the oxidation of phenylsulfinylacetic acids by Iron(III) polypyridyl complexes in the SDS micellar media, R. Jeevi Esther Rathnakumari, C. Kavitha, J. Janet Silvia Jebarose, P. Subramaniam, C. Vetriselvi, J. Emerg. Technol. Innov. Res., 11(5) c773-c785, (2024).

Non-linear Hammett in the SDS mediated electron transfer reactions in the oxidation of phenylsulfinylacetic acid by Iron(III) polypyridyl complexes, R. Jeevi Esther Rathnakumari, C. Kavitha, J. Janet Silvia Jebarose, P. Subramaniam, C. Vetriselvi, J. Creat. Res. Thoughts., 12(5), c633-c645, (2024).

Triton X-100 micellar effects and Kinetic models in the oxidation of Phenylsulfinylacetic acids by Iron(III) polypyridyl complexes, R. Jeevi Esther Rathnakumari, C. Kavitha, J. Janet Silvia Jebarose, P. Subramaniam, C. Vetriselvi, J. Emerg. Technol. Innov. Res., 11(5), h202-h18, (2024).

SDS mediated electron transfer reactions and the kinetic models in the oxidation of phenylsulfinylacetic acids by Iron(III) polypyridyl complexes, R. Jeevi Esther Rathnakumari, C. Kavitha, J. Janet Silvia Jebarose, P. Subramaniam, C. Vetriselvi, Int. J. Creat. Res. Thoughts. 12(5), f139-f152 (2024).

Details about the research papers published by Dr. K. Jacinth Mispa

Microwave- assisted route for synthesis of nanosized metal sulphides, K. Jacinth Mispa, P. Subramaniam and R. Murugesan, Chalcogenide Letters, 7 (5) 335-340 (2010)
Characterization of polyindole/ZnO nanocomposites, K. Jacinth Mispa, P. Subramaniam and R. Murugesan, Int. J. Nanotechnol. Appl., 4 ,147-152 (2010).
Oxidative Polymerization of Aniline Using Zirconium Vanadate, a Novel Polyaniline Hybrid Ion Exchanger. K. Jacinth Mispa, P. Subramaniam and R. Murugesan, Designed Monomers and Polymers, 14(5), 423–432(2011)
Synthesis and characterization of polyindole/CuO nanocomposites, K. Jacinth Mispa, P. Subramaniam and R. Murugesan, Nano Trends, 15, 9-16 (2013).

Studies on ion-exchange properties of polyaniline Zr(IV) tungstoiodo-phosphate Nanocomposite Ion Exchanger, K. Jacinth Mispa, P. Subramaniam and R. Murugesan, J. Polymers, 2013, 1-12 (2013).

Studies on polyaniline/silver molybdate nanocomposites, K. Jacinth Mispa, P. Subramaniam and R. Murugesan, Inter. J. Nanoscience, 1, 1 (2014).

Ion-exchange behavior of new and novel Zirconium(IV)-based. composite cation-exchangers, K. Jacinth Mispa, R. Muthulakshmi, C. Prathees Kumar,
P. Subramaniam and R. Murugesan, Poly. Plast. Technol. Eng., 56, 55-70 (2017).

Development and physico-chemical characterization of conducting polymeric zirconium based advanced nanocomposite ion-exchangers for environmental remediation, K. Jacinth Mispa, K. Anusiya, P. Subramaniam and R. Murugesan, Nano Hybrids and Composites, 20, 121-148 (2018).

Development and characterization of polyaniline/titanium conducting polymer based ion exchange material for removal of toxic metal ions, T. Amutha and K. Jacinth Mispa, Int. J. Environ. Anal. Chem., (2020).

Poly(O-Toluidine)/Zirconium-based nanocomposite ion-exchangers for water treatment and environmental remediation, K. Jacinth Mispa, C. Regini, P. Subramanaiam and R. Murugesan, J. Water. Environ, Nanotechnol., 5(1), 17-33 (2020).

Synthesis of novel PANI based Ti (IV) phosphosulphosalicylate composite cation exchanger –structural, electrical and impedance properties, T. Amutha and K. Jacinth Mispa, J. Adv. Dielectr. 11, 215008-215019 (2021)

Potential utility and design approach on novel mesoporous polyaniline functionalized ternary composite cation exchanger, R. Umadevi and K. Jacinth Mispa, J. Mol. Struct,1246, 131037 (2021)

Fabrication, Characterisation, Ion-Exchange Studies and Binary Separation of Polyaniline/Ti(IV) iodotungstate Composite Ion-Exchanger for the Treatment of Water Pollutants, T. Kodispathi and K. Jacinth Mispa, Environ. Nanotechnol. Monit. Manag. 100555 (2021).

Sol-gel synthesis, physico-chemical characterization and investigations on ion exchange performance of atypical conducting polymer integrated composite cation exchangers, K. Jacinth Mispa and R. Umadevi, Sep. Sci. Technol., 58(12), 2145-2165 (2023).

Ion exchange behavior of novel Pani -Ti(IV) phosphosulphosalicylate hybrid cation exchange material for the selective separation of Pb(II) in environmental remediation, K. Jacinth Mispa and T. Amutha, Poly. Plast. Technol. Mat., 62(1), 1-18 (2023)

Titanium-embedded nanocomposite material stimulates ion-exchange characteristics to deal with toxic heavy metal pollutants in aquatic environment, T. Kodispathi and K. Jacinth Mispa Sep. Sci.Technol.,, 58(17–18), 2932–2949 (2023)

Details about the research papers published by Dr. P. Deepa Rani

Eugenia Jambolana Used as Corrosion Inhibitor on Mild Steel in 1N Hydrochloric Acid Medium, P. Deepa rani, A. Petchiammal, M. Pirammarajeswari, C. Rajeswari and S. Selvaraj, American Journal of Phytomedicine and Clinical Therapeutics, 215-225 (2013).
The effect of Eugenia jambolana on Zinc in 1.0N Hydrochloric acid environment, P. Deepa rani, A. Petchiammal, S. Selvaraj, T. Nanthini and S. Mariammal, International Journal of Green and Herbal Chemistry, 2(3), 510-521 (2013).
Electrochemical behaviour of Solanum trilobatum plant extract on stainless steel in natural sea water environment, P. Deepa rani and S. Selvaraj, Annalen der Chemischen Forschung, 1(3), 1-9 (2013).
Electrochemical behavior of jatropha curcas plant extract on brass in hydrochloric acid medium, P. Deepa rani, S. Selvaraj, Indian Journal of Applied Research 4(5), 59-61 (2014)
Corrosion behaviour of Sauropus Androgynus Leaves (SAL) on mild steel in natural sea water, P. Deivanayagam, I. Malarvizhi, S. Selvaraj and P. Deeparani, International Journal of Advances in Pharmacy, Biology and Chemistry, 4(3), 1-11 (2015).
Corrosion inhibition efficacy of ethanolic extract of mimusops elengi leacyes (MEL) on Copper in Natural sea water, P. Deivanayagam, I. Malarvizhi, S. Selvaraj and P. Deeparani, International Journal of Multidisciplinary Research and Development 2(4), 100-107 (2015).
Corrosion inhibition of mild steel in acid medium using talinum fructicosum as an eco-friendly inhibitor, S. Michlin Ruphina Maragatham, A. Bright, P. Deeparani, I. Malarvizhi, S. Selvaraj, J. Emerg. Technol. Innov. Res., 5(15) 727-733 (2018).
Dissolution behavior of mild steel using raphanus sativus extract in 1n hydrochloric acid medium, S. Michlin Ruphina Maragatham, A. Bright, P. Deeparani, I. Malarvizhi, S. Selvaraj, Int. J. Res. Anal. Rev., 5(4), 229-238 (2018)
Indigofera Tinctoria Leaf (ITL) as an apt inhibitor, for mild steel dissolution in acid media, S. Michlin Ruphina Maragatham, A. Bright, P. Deeparani, I. Malarvizhi, S. Selvaraj, International Journal of Scientific Research and Review, 8(1), 646-654 (2019)
Activities of Couroupita Guianensis Flower Extract on Carbon Steel in Acid by Electrochemical Studies, C. Sangeetha, P. Deepa Rani, S. Selvaraj, and K. Kalirajan, International Journal of Scientific Research and Review, 8(1), 2698-2706 (2019).
Evaluation of corrosion inhibition performance of Stachytarpheta jamaicensis leaf extract on mild steel in 1.0 N HCl using electrochemical studies, C. Sangeetha, Mathu Sudhan, P. Deepa Rani, S. Selvaraj, and K. Kalirajan, Int. J. Res. Anal. Rev., 6(2), 649-655 (2019).
Jatropha gossyfolia– A Green Inhibitor Act as Anticorrosive Agent on Carbon Steel, C. Sangeetha, C. Chinnakani, P. Deepa Rani and S. Selvaraj, J Adv. Sci. Res., 11 (1), 180-186 (2020).
Inhibitive Action of Eleaocarpus Serratus Leaf Extract on Mild Steel in Acid Medium, C. Sangeetha, P. Deepa Rani, S. Selvaraj, and K. Kalirajan, AEGAEUM JOURNAL, 8(5), 53-62 (2020).
Protective effect of Toddaliaasatica leaf extract on Mild steel in 1.0N HCl, C. Sangeetha, P. Deepa Rani, S. Selvaraj, and K. Kalirajan, Journal of Advanced Applied Scientific Research, 3(4), 1-10 (2020).
Morphological and electro – chemical approaches of mild steel in acid media using green inhibitor Michlin Ruphina Maragatham, A. Bright, P. Deeparani, I. Malarvizhi, S. Selvaraj, Studia Research, Journal of the Study of Research, 12(1) 97-106 (2020).
Corrosion behaviour of sodium methane sulfinate inhibitors on gas pipeline metal in natural seawater environment. M. Mathu Sudhan, P. Deepa Rani, S. Selvaraj, K. Kalirajan, I. Malarvizhi, Neuro Quantology, 20(11), 5440-5454 (2022).
Inhibition studies on Mild steel using stachytarphyta Jamainensis leaf extract., C. Sangeetha, P. Deepa Rani, Neuro Quantology, 20(2), 2549-2555 (2022).
Corrosion Inhibition of Momordica Cymbalaria Extract on Oil and Gas pipeline Steel in Acidic Environment, P. Bala, I. Malar vizhi, K. Kalirajan, S. Selvaraj, P. Deepa Rani, Neuro Quantology 20 (16), 1232-1245 (2022).
Electrochemical and adsorption studies of p-Tolyl sulfoxide inhibitor on gas pipeline metal in natural sea water environment, M. Mathu Sudhan, P. Deepa Rani, Eur. Chem. Bull, 12(S3), 5251-5270 (2023).
Adsorption and electrochemical Behavior of cyperus rotundus on oil And gas pipeline steel in1.0N Hydrochloric acid, P. Bala, C. Sangeetha, K. Kalirajan, P. Deepa Rani, Eur. Chem. Bull.., 12 (S3), 2029 – 2044 (2023).

Details about the research papers published by Dr. I. Abulkalam Azath

Palladium nanoparticles embedded on thiourea-modified chitosan: a green and sustainable heterogeneous catalyst for the Suzuki reaction in water, A. Affrose, P. Suresh, I. Abulkalam Azath, and K. Pitchumani, RSC Adv., 5, 27533-27539 (2015).
Oxidative hydroxylation of arylboronic acids to phenols catalyzed by copper nanoparticles ellagic acid composite, A. Affrose, I. Abulkalam Azath, A. Dhakshinamoorthy and K. Pitchumani, J. Mol. Cat. A: Chemical, 395, 500-515 (2014).
A ratiometric tetrazolylpyridine based “turn-on” fluorescent chemosensor for Zn²⁺ ion in aqueous media, P. Kaleeswaran, I. Abulkalam Azath, V. Tharmaraj and K. Pitchumani, ChemPlusChem., 79, 1361-1366 (2014).
Flavone Modified-b-cyclodextrin as a highly selective and efficient fluorescent chemosensor for Cu²⁺ ions and L-Histidine, I. Abulkalam Azath and K. Pitchumani, Sensors and Actuators B: Chem., 188, 59-64 (2013).

Details about the research papers published by Dr. A. Antony Muthu Prabhu

Investigation of 3D Contour Map and Intermolecular Interaction of Dopamine with b-Cyclodextrin and 2-Hydroxypropyl- b-cyclodextrin, A. Antony Muthu Prabhu, Madi Fatiha, Nouar Leila, T. Anantha Raj, Inmaculada Navarro-Gonza´lez, Maria Jesu´s Periago, Maria Josefa Ya´n˜ez-Gasco´n and Horacio Pe´rez-Sa´nchez, Journal of Solution Chemistry, 47, 409-429 (2018).

Effect of natural and modified cyclodextrins on the excited state proton transfer of 7-hydroxy-4-methylcoumarin, A. Antony Muthu Prabhu, Madi Fatiha, B. Sivaraman, Maria Josefa Yáñez-Gascón and Horacio Pérez-Sánchez, Journal of Molecular liquids, 268, 911-924 (2018).

Inclusion Complexation of Benzanilide and Fast Violet B with β-cyclodextrin – A Theoretical Approach, A. Antony Muthu Prabhu, Organic Chemistry Plus, 1, 23-28 (2020).

Equilibrium constant, concentrations study of p-aminobenzoic acid in anionic, cationic and non-ionic surfactants, A. Antony Muthu Prabhu, N. Rajendiran and K. Sathiyaseelan, Science Journal of Analytical Chemistry, 9, 68-76 (2021).

Spectral and theoretical investigation of inclusion complex between cinnamic acid and hydroxycinnamic acids with native cyclodextrins, N. Rajendiran, A. Antony Muthu Prabhu, T. Mohandoss, J. Thulasidhasan and R. Baskaran, Polycyclic aromatic compounds, Accepted (2021).
Structural aspects and stability of interactions between phenyl-3,3’-bis(indolyl)methanes and b-cyclodextrin from density functional theory, A. Antony Muthu Prabhu, Fatiha Madi, Nouar Leila, G.S. Suresh Kumar and K. Sathiyaseelan, Polycyclic Aromatic Compounds, 43, 5276-5298 (2023).

Investigation of Ag and Ag/Co bimetallic nanoparticles with naproxen-cyclodextrin inclusion complex, A. Mani, P. Ramasamy, A. Antony Muthu Prabhuand N. Rajendiran, Journal of Molecular Structure, 1284, 135301 (2023).

Encapsulation through concern of inter and intramolecular hydrogen bonding of 2-hydroxy benzoic acid with C-alkyl calix[4]resorcinarenes, K. Sathiyaseelan and A. Antony Muthu Prabhu, Journal of Molecular Structure, 1292 136093 (2023).

Photophysical, antioxidant, antibacterial and NBO, LOL, ELF analysis of alkyl groups substituted calix[4]resorcinarenes, Kasi Sathiyaseelan, A. Antony Muthu Prabhu and Narayaswamy Rajendiran, Journal of Fluorescence, 34, 885-903 (2024).
Formation of inclusion complexes of 2-hydroxypropyl β-cyclodextrin with 2-hydroxychalcone: Experimental and theoretical study, J. Allwyn Jeyadurai, P. Muthuselvan, A. Antony Muthu Prabhu, N. Rajendiran and Arish Dasan, Polycyclic Aromatic Compounds, Accepted (2024).
Interactions between diphenylamine with 2-hydroxypropyl β-cyclodextrin based on spectral, biological and theoretical investigations, A. Antony Muthu Prabhu, G.S. Suresh Kumar, N. Rajendiran, K. Sathiyaseelan and M. Balamathi, Journal of Macromolecular Science, Part B, 63, 536-569 (2024).
Synthesis and analysis of Ag/olanzapine/cyclodextrin and Ag/Co/olanzapine/cyclodextrin inclusion complex nanorods, A. Mani, P. Ramasamy, A. Antony Muthu Prabhu, P. Senthilraja and N. Rajendiran, Physics and Chemistry of liquids, 62, 196-209 (2024).

Details about the research papers published by Dr. A. Ramdass:

Electron transfer studies of ruthenium(II) complexes with biologically important phenolic acids and tyrosine., A. Rajeswari, A. Ramdass, P. Muthu Mareeswaran and S. Rajagopal,J. Fluoresc., 26, 531–543 (2016).
Electron transfer reactions of osmium(II) complexes with phenols and phenolic acids,
A. Rajeswari, A. Ramdass, P. Muthu Mareeswaran and S. Rajagopal, J. Mol. Struct., 1115, 75-84 (2016)
Label Free Luminescence Strategy for Sensitive Detection of ATP using Aptamer-Ru(II) complexes, E. Babu, P. Muthu Mareeswaran, A. Ramdass, P. Ramesh, S. Rajagopal, J. Lumin., 175, 267-273 (2016).
Synthesis and Photophysical Properties of Rhenium(I)-alkynyl Molecular Rectangles,
A. Ramdass, V. Sathish, Bala. Manimaran, P. Thanasekaran, S. Rajagopal, Orient. J. Chem., 32, 1859–1873 (2016).
Sensing of insulin fibrillation using alkoxy-bridged binuclear rhenium(I) complexes, V. Sathish, A. Ramdass, Z.-Z. Lu, M. Velayudham, P. Thanasekaran, K.-L. Lu, S. Rajagopal, Inorg. Chem. Commun., 73, 49–51 (2016).
Electron transfer reactions of ruthenium(II) complexes with polyphenolic acids in micelles, A. Rajeswari, A. Ramdass, P. Muthu Mareeswaran, S. Rajagopal, J. Lumin., 170, 8–16 (2016).
Luminescent sensor for copper(II) ion based on imine functionalized monometallic rhenium(I) complexes, A. Ramdass, V. Sathish, M. Velayudham, P. Thanasekaran, S. Umapathy, S. Rajagopal, Sens. Actuators, B 240, 1216–1225 (2017).
Development of luminescent sensors based on transition metal complexes for the detection of nitroexplosives, V. Sathish, A. Ramdass, M. Velayudham, Kuang-Lieh Lu, P. Thanasekaran, S. Rajagopal, Dalton Trans., 46, 16738–16769 (2017).
Recent Developments on Optical and Electrochemical Sensing of Copper(II) Ion Based on Transition Metal Complexes, A. Ramdass, V. Sathish, E. Babu, M. Velayudham, P. Thanasekaran, S. Rajagopal, Coord. Chem. Rev. 343, 278–307 (2017).
Aggregation Induced Emission Enhancement (AIEE) of Anthracene based Schiff Base Compounds and their Applications as Sensor for BSA and Optical Cell Imaging, D. Simon, C.-H. Chang, C.-L. Chen, A. Mathavan, A. Ramdass, V. Sathish, P. Thanasekaran, W.-S. Li, S. Rajagopal, Lumin., 33, 780–789 (2018).
Phosphorescence “Turn-On” Sensing of Anions by Rhenium(I) Schiff-base Complexes,
A. Ramdass, V. Sathish, M. Velayudham, P. Thanasekaran, S. Rajagopal, Chemistry Select, 3, 2277–2285 (2018).
Utilization of Heavy Metal Complexes As Phosphorogenic Sensors for the Detection of Amino Acids, A. Ramdass, V. Sathish, P. Thanasekaran, Orient. J. Chem., 34, 01-23 (2018).
AIE or AIE(P)E-active transition metal complexes for highly sensitive detection of nitroaromatic explosives, A. Ramdass, V. Sathish, P. Thanasekaran, Results Chem., 4, 100337 (2022).
Structural behavior of rhenium complexes in fluoride sensing: a spectroscopic and computational study, M. Velayudham, A. Ramdass, V. Sathish, S. Rajagopal, Struct. Chem., 33, 1041–1053 (2022).

Details about the research papers published by Dr. P. Subramaniam

Calcination of red soil and black soil used for the degradation of aniline blue dye, P. Muhambihai, V. Rama and P. Subramaniam, Inter. J. Sci. Res. Rev., 8, 1714-1726 (2019)

Antimicrobial screening of oxovanadium(IV)complexes against human pathogens, R. Jeevi Esther Rathinakumari, J. Janet Sylvia Jabarose, P. Subramaniam andC. John Wesly Kirubakaran, Int. J. Res. Anal. Rev., 6, 506-511 (2019)

Synergistic interaction of mixed micelles evidenced by kinetic investigation, J. Janet Sylvia Jabarose, R. Jeevi Esther Rathinakumari and P. Subramaniam, Int. J. Res. Anal. Rev., 6, 492-500 (2019)

A comparative study of ion exchange behavior and analytical applications of zirconium and tin based polyaniline hybrid cation exchangers, N. Kohila and P. Subramaniam, Reactive and Functional Polymers, 144, 104341- 104354(2019)

Spectral, thermal, fluorescence and antimicrobial studies of binuclear Mn(II) Complexes with bis-(Carboxyamides) derived from 4,4’-diaminobiphenyl, 1,4-diaminobenzene with anhydrides, M. Maria Albert Denison, D. Kanagavel and P. Subramaniam, Inter. J. Res. Advent Tech., 6, 2560-2667 (2018).

Synthesis, spectral characterization and antimicrobial properties of binuclear bis-(carboxyamides) with oxovanadium(IV) coordination compounds, M. Maria Albert Denison, D. Kanagavel and P. Subramaniam, Inter. J. Sci. Res. Rev. 7, 695-703 (2018).

Development and physico-chemical characterization of conducting polymeric zirconium based advanced nanocomposite ion-exchangers for environmental remediation, K. Jacinth Mispa, K. Anusiya, P. Subramaniam and R. Murugesan, Nano Hybrids and Composites, 20, 121-148 (2018).

Kinetic study on the oxidation of phenyl vinyl sulfide with iron(III)-polypyridyl complexes in the presence of anionic micelle, P. Balakumar, S. Balakumar, P. Subramaniam and D. Sweetlin Rajula Rubavathi, Int. J. Chem Tech Res., 11, 262-264 (2018).

Effect of additives on electrodeposition of zinc and zinc-cobalt alloy in non-cyanide alkaline bath, S. Selvakumari, M. Chandran, S. Premlatha, G. N. K. Ramesh Bapu and P. Subramaniam, J. Res. in Sci., 3, 45-50 (2017).

Effect of additives on morphology texture and corrosion resistance of electrodeposited zinc and zinc-cobalt alloy, S. Selvakumari, M. Chandran, S. Premlatha, G. N. K. Ramesh Babu and P. Subramaniam, Int. J. Eng. Res. Devel., 13, 21-31 (2017).

Oxidative decarboxylation reaction between phenylsulfinylacetic acids and [Fe^III(salen)Cl] complex in TX-100 medium, P. Subramaniam and C. Shanmuga Sundari, J. Chem & Cheml. Sci., 7, 486-494 (2017).

Arsenic removal using silver-impregnated Prosopis spicigera L. wood (PSLW) activated carbon: Batch and column studies, M. Murugan, M. Jansi Rani, P. Subramaniam and E. Subramanian, J. Appl. Sci. Environ. Manage., 21, 1307-1312 (2017).

Stability studies on solution equilibria of Zn(II) pyrimidine nucleus bases, S. Shobaba, P. Subramaniam, J. Dharmajara, S. Aravind Narayan and L. Mitu, Bul. Chem. Comm., 49, 347-353 (2017).

Ion-exchange behavior of new and novel zirconium(IV)-based. composite cation-exchangers, K. Jacinth Mispa, R. Muthulakshmi, C. Prathees Kumar,
P. Subramaniam and R. Murugesan, Polymer-Plastics Technology and Engineering, 56, 55-70 (2017).

Modulation of catalytic activity by ligand oxides in the sulfoxidation of phenylmercaptoacetic acids by oxo(salen)chromium(V) complexes, P. Subramaniam, S. Anbarasan, S. Sugirtha devi and A. Ramdass, Polyhedron, 119, 14-22 (2016).

Importance of ground state stabilization in the oxovanadium(IV)-salophen mediated reactions of phenylsulfinylacetic acids by hydrogen peroxide-Nonlinear Hammett correlation, P. Subramaniam, R. Jeevi Esther Rathinakumari and J. Janet Sylvia Jaba Rose, Polyhedron, 117, 496-503 (2016).

A paradigm shift in rate determining step from single electron transfer between phenylsulfinylacetic acids and iron(III) polypyridyl complexes to nucleophilic attack of water to the produced sulfoxide radical cation: a non-linear Hammett, P. Subramaniam, J. Janet Sylvia Jaba Rose and R. Jeevi Esther Rathinakumari, J. Phy. Org. Chem., 29, 496-504 (2016).

Electrophilic and nucleophilic pathways in ligand oxide mediated reactions of phenylsulfinylacetic acids with oxo(salen)chromium(V) complexes, P. Subramaniam, S. Sugirtha devi and S. Anbarasan, Polyhedron, 115, 164-173 (2016).

Stability and structural studies on Ni(II)-5-fluorouracil mixed ligand complex systems, S. Shobana, P. Subramaniam, J. Dharmaraja and S. Arvindnarayan, J. Solution Chem., 45, 334-358 (2016).

Study of water soluble dyes adsorption from aqueous solution by Prosopis spicigera L. wood (PSLW) carbon, M. Jansi Rani, M. Murugan, P. Subramaniam and E. Subramanian, Indian J. Chem. Tech., 23, 22-30 (2016).

Picolinic acid promoted oxidative decarboxylation of phenylsulfinylacetic acid by Cr(VI), P. Subramaniam and N. Thamil Selvi, Bull. Chem. Soc. Ethiop., 30, 137-146 (2016).

Dynamics of cetyltrimethylammonium bromide-mediated reaction of phenylsulfinylacetic acid with Cr(VI): Treatment of pseudo-phase models, P. Subramaniam and N. Thamil Selvi, J. Serb. Chem. Soc., 80, 1019-1034 (2015).

Kinetic Study on the Oxidation of Phenyl Vinyl Sulfide with Iron(III)-Polypyridyl Complexes in the Presence of Non-Ionic Micelle, P. Balakumar, S. Balakumar and P. Subramaniam, Chem. Tech Res., 8, 603-606 (2015).

Structural, morphological and biological investigations of some transition metal-5-Fluorouracil-amino acid mixed ligand complexes, S. Shobana, P. Subramaniam, J. Dharmaraja and S. Arvind Narayan, Inorganica Chemica Acta, 435, 244-261 (2015).

Interaction of pyridine-2,6-dicarboxylic acid with Cr(VI) in the oxidative decarboxylation of phenylsulfinyl acetic acid and linear free energy relationship, P. Subramaniam and N. Thamil Selvi, Amer. Chem. Sci. J., 6, 105-114 (2015).

Spectroscopic study of bifenox complexation with α-, β- and γ-cyclodextrin in solution and solid state, Pushpa R Gopalan, P. Subramaniam and A.G. Annaselvi, Amer. Chem. Sci. J., 6, 115-125 (2015).

Synthesis, structural elucidation, biological, antioxidant and nuclease activities of some 5-Fluorouracil-amino acid mixed ligand complexes, S. Shobana, P. Subramaniam, L. Mitu, J. Dharmaraja and S. Arvind Narayan, Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 134, 333-344 (2015).

Role of Iron(III)-salen chloride as oxidizing agent with thiodiglycolic acid: The Effect of Axial Ligands, P. Subramaniam, T. Vanitha, T. Kodispathi and C. Shanmuga Sundari, J. Mex. Chem. Soc., 58, 211-217 (2014).

Micellar and substituent effects on the redox reactions of phenylsulfinylacetic acid and Cr(VI) in SDS Medium, P. Subramaniam and N. Thamil Selvi, Inter. J. Adv. Sci. Tech. Res., 4, 418-427 (2014).

A study on water hyacinth Eichhornia crassipes as oil sorbent, M. Jansi Rani, M. Murugan, P. Subramaniam and E. Subramanian, J. Appl. Nat. Sci., 6, 134-138, (2014).

Proximal effect of the nitrogen bases in the oxidative decarboxylation of phenylsulfinylacetic acids by oxo(salen)chromium(V) complexes, P. Subramaniam, S. Sugirtha Devi and S. Anbarasan, J. Mol. Catalysis A: Chemical, 390, 159-168 (2014).

Studies on polyaniline/silver molybdate nanocomposites, K. Jacinth Mispa, P. Subramaniam and R. Murugesan, Inter. J. Nanoscience, 1, 1 (2014).

Synthesis and structural elucidation of Cu(II)-pyrimidine-amino acid mixed ligand complex: spectral, morphological, thermo and electro-chemical studies, S. Shobana, P. Subramaniam and S. Arvind Narayan, J. Emerging Tech. Mech. Sci. Eng. 5, 201-205 (2014).

Fluoride removal from aqueous solution using batch, column and home water treatment method by low cost adsorbent : Prosopis spicigera L. Wood (PSLW) Carbon, M. Murugan, M. Jansi Rani, P. Subramaniam and E. Subramanian, Indian J. Envir. Prot., 34, 207-216 (2014).

Morphological and pharmacological investigation on some biopotent materials derived from substituted pyrimidine and imidazole enzyme constituents, S. Shobana, P. Subramaniam, J. Dharmaraja and A. Narayan, Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 126, 242-253 (2014).

Adsorptive removal of arsenic from aqueous solution on PSLW carbon (Prosopis spicigera L. wood): Equilibrium, kinetics, thermodynamics and home water treatment studies, M. Jansi Rani, M. Murugan, P. Subramaniam and E. Subramanian, Res. J. Chem. Environ., 18, 16-24 (2014).

Spectral and mechanistic investigation of oxidative decarboxylation of phenylsulfinylacetic acid by Cr(VI), P. Subramaniam, N. Thamil Selvi and S. Sugirtha Devi, J. Korean Chem. Soc., 58, 17-24 (2014).

Spectroscopic investigation on kinetics, thermodynamics and mechanism for electron transfer reaction of iron(III) complex with sulphur centered radical in stimulated biological system, S. Deepalakshmi, A. Sivalingam, T. Kannadasan, P. Subramaniam, P. Sivakumar and S. T. Brahadeesh, Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 124, 315-321 (2014).

Assessment of the adsorption kinetics and equilibrium for the potential removal of direct Yellow-12 dye using Jatropha Curcus L. activated carbon, G. Revathi, S. Ramalingam and P. Subramaniam, Chem. Sci. Trans., 3, 93-106 (2014).

Studies on the preparation and characterization of β-cyclodextrin-picric acid inclusion complexes, P. R Gopalan, A.G. Annaselvi and P. Subramaniam, Inter. J. Agri. Food Sci., 3, 90-94 (2013).

Studies on ion-exchange properties of polyaniline Zr(IV) tungstoiodo-phosphate Nanocomposite Ion Exchanger, K. Jacinth Mispa, P. Subramaniam and R. Murugesan, J. Polymers, 2013, 1-12 (2013).

Spectral evidence for the one-step three-electron oxidation of phenylsufinylacetic acid and oxalic acid by Cr(VI), P. Subramaniam and N. Thamil Selvi, Amer. J. Anal. Chem., 4, 20-29 (2013).

Synthesis and characterization of b-cyclodextrin capped silver nanoparticles, Pushpa R Gopalan, A. G. Annaselvi and P. Subramaniam, Inter. J. Nanomat. Biostru., 3, 26-30 (2013).

Preparation and characterization of inclusion complexes of isoproturon with native and modified β-cyclodextrins, Pushpa R Gopalan, A. G. Annaselvi and P. Subramaniam, Inter. J. Agri. Food Sci., 2, 164-169 (2012).

Application of the Marcus theory to the electron transfer reaction between benzylthioacetic acid and tris(1,10-phenanthroline)iron(III) perchlorate, P. Balakumar, S. Balakumar and P. Subramaniam, Reac. Kinet. Mech. Cat., 107, 253–261 (2012).

Importance of hydrophobic interaction in the micellar catalysed diphenyl sulfide oxidation with Iron(III)bipyridyl complex, P. Balakumar, S. Balakumar and P. Subramaniam, Der Chemica Sinica, 3, 959-964 (2012).

Adsorption of basic dyes onto activated carbon prepared from teak leaf, N. Kannan, A. Vijayakumar and P. Subramaniam, Indian J. Envir. Prot., 31, 552-559 (2011).

Removal of Direct Yellow-12 Dye from Water by Adsorption on Activated Carbon Prepared from Ficus Racemosa L, G. Revathi, S. Ramalingam, P. Subramaniam and A. Ganapathi, E-Journal of Chem.,8,1536-1545 (2011).

Kinetics of adsorption of direct Yellow 12 Dye from aqueous solution by jack fruit leaf carbon, G. Revathi, S. Ramalingam and P. Subramaniam, Int. J. Chem. Sci.: 9, 524-536 (2011).

Oxidative polymerization of aniline using zirconium vanadate, a novel polyaniline hybrid ion exchanger, K. Jacinth Mispa, P. Subramaniam and R. Murugesan, Designed Monomers and Polymers, 14, 423–432 (2011).

Adsorptive removal of Acid Red-114 dye by activated carbon prepared from Kattamanakku tree leaves (Jatropha Curcas L), G. Revathi, S. Ramalingam, P. Subramaniam, A. Ganapathi and R. Valliappan, Orient. J. Chem., 26, 1385-1391 (2010).

Removal of DNB-106 dye from dye wastewater using Athi tree leaf powder carbon (Ficus Racemosa) by adsorption, G. Revathi, S. Ramalingam, P. Subramaniam, A. Ganapathi and R. Valliappan, Orient. J. Chem., 26, 1407-1412 (2010).

Detoxification studies on the removal of Malachite Green using teak leaf material, N. Kannan, A. Vijayakumar and P. Subramaniam, Indian J. Envir. Prot., 30, 761-767 (2010).

Synthesis and characterization of polyindole / ZnO nanocomposites, K. Jacinth Mispa, P. Subramaniam and R. Murugesan, Int. J. Nanotech. Appl., 4, 147-152 (2010).

Microwave-assisted route for synthesis of nanosized metal sulphides, K. Jacinth Mispa, P. Subramaniam and R. Murugesan, Chalcogenide Lett., 7, 335-340 (2010).

Studies on the removal of red industrial dye using teak leaf, Maize corn and Babool Tree Bark Carbons – A Comparison, N. Kannan, A. Vijayakumar and P. Subramaniam, E-J. Chem., 7, 770-774, (2010).

Electron transfer reaction of Iron(III)-bipyridyl complex with diphenyl sulfide, P. Balakumar, S. Balakumar and P. Subramaniam, Asian J. Chem., 22, 5723-5729 (2010).

Details about the research papers published by Dr. S. Anbarasan

Modulation of catalytic activity by ligand oxides in the sulfoxidation of phenylmercaptoacetic acids by oxo(salen)chromium(V) complexes, P. Subramaniam, S. Anbarasan, S. Sugirtha devi and A. Ramdass, Polyhedron, 119, 14-22 (2016).

Electrophilic and nucleophilic pathways in ligand oxide mediated reactions of phenylsulfinylacetic acids with oxo(salen)chromium(V) complexes, P. Subramaniam, S. Sugirtha devi and S. Anbarasan, Polyhedron, 115, 164-173 (2016).

Proximal effect of the nitrogen bases in the oxidative decarboxylation of phenylsulfinylacetic acids by oxo(salen)chromium(V) complexes, P. Subramaniam, S. Sugirtha Devi and S. Anbarasan, J. Mol. Catalysis A: Chemical, 390, 159-168 (2014).